Organic chem, resonance structure

In summary, resonance is a concept in organic chemistry where a molecule or ion can have multiple possible structures due to the delocalization of electrons. These structures, known as resonance structures, contribute to the stability of a molecule by distributing the charge and delocalizing the electrons. They can also result in different bond lengths within the molecule. The major resonance contributor is the most stable resonance structure, determined by following the rules of resonance theory. Resonance can only occur in molecules with conjugated systems, such as benzene, butadiene, and nitromethane.
  • #1
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Homework Statement


Are these two structures resonance?

if not why not?

res.jpg



Homework Equations





The Attempt at a Solution



I drew these resonance forms myself, but the answer book didnt' have this resonance structure in its answer and i wanted to know if this indeed is a resonance form.

I ask because one has total charge of -2 and other one is neutral
 
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  • #2
No, they aren't resonance structures. The reason is:
one has total charge of -2 and other one is neutral

Resonance forms don't result in a net change of charge. That's a redox effect...
 
  • #3


Resonance structures refer to the different possible ways in which the atoms in a molecule can be arranged while maintaining the same overall connectivity. These structures are represented by drawing multiple Lewis structures, each with different arrangements of electrons and formal charges. In order for two structures to be considered resonance structures, they must have the same overall connectivity and differ only in the placement of electrons and formal charges.

Based on this definition, it is not clear if the two structures provided are resonance structures or not, as there is no information about the overall connectivity of the atoms. However, if the two structures have the same overall connectivity and differ only in the placement of electrons and formal charges, then they can be considered resonance structures. The fact that one structure has a total charge of -2 and the other is neutral does not necessarily mean they cannot be resonance structures, as the overall charge can change between resonance structures. It is important to note that resonance structures are not individual molecules, but rather different representations of the same molecule.
 

Related to Organic chem, resonance structure

1. What is resonance in organic chemistry?

Resonance is a concept in organic chemistry where a molecule or ion can have multiple possible structures due to the delocalization of electrons. These structures are referred to as resonance structures and can be represented using Lewis structures or molecular orbital diagrams.

2. How do resonance structures affect the stability of a molecule?

Resonance structures contribute to the stability of a molecule by distributing the charge and delocalizing the electrons, resulting in a more stable overall structure. This is known as resonance stabilization.

3. Can resonance structures have different bond lengths?

Yes, resonance structures can have different bond lengths because the delocalization of electrons can result in partial double bonds and single bonds in different locations within the molecule.

4. How do you determine the major resonance contributor?

The major resonance contributor is the most stable resonance structure, which is determined by following the rules of resonance theory, such as the octet rule and minimizing formal charges.

5. Can resonance occur in all molecules?

No, resonance can only occur in molecules with conjugated systems, which are molecules that have alternating single and multiple bonds. Examples include benzene, butadiene, and nitromethane.

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