Normalisation and normalising wavefunctions

In summary, normalisation is a mathematical technique in quantum mechanics used to calculate probabilities by ensuring that the total probability of finding a particle in infinite space is equal to one. This is done by finding the value of a constant that makes the wave function satisfy a specific equation. Normalisation does not have any physical significance in the wave equation, but it is important for mathematical calculations of probability in quantum mechanics.
  • #1
indeterminate
3
0
In our physics class of quantum mechanics, we constantly talk about normalisation and normalising wavefunctions such that the total probability of finding the particle in infinite space is one. I don't get why do we normalise and how do we normalise(I have not taken up statistics course). It would also be benificial if you can provide me with external links.
 
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  • #2
indeterminate said:
why do we normalise

If the wave function ψ is normalized, then we can calculate the probability that the particle lies between x=a and x=b (in the one-dimensional case) simply by evaluating the integral $$P(a \leq x \leq b) = \int^b_a {\psi^*\psi dx}$$

and how do we normalise

An un-normalized ψ has an arbitrary constant overall multiplicative factor, call it A. For example, we might have $$\psi(x) = Ae^{-x^2}$$ To normalize ψ, we find the value of A that makes this equation true: $$\int^{+\infty}_{-\infty} {\psi^*\psi dx} = 1$$ That is, we evaluate the integral, whose result must include a factor of A2, solve the equation for A, and finally substitute our newly-found value of A back into the original formula for ψ.
 
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  • #3
so, basically normalisation is a technique which helps in mathematical calculations of probability. It has no physical significance in the wave equation.
 
  • #4
indeterminate said:
so, basically normalisation is a technique which helps in mathematical calculations of probability. It has no physical significance in the wave equation.
As long as you always evaluate expectation values as [tex]\langle A\rangle = \frac{\langle \Psi|\hat A|\Psi\rangle}{\langle\Psi|\Psi|\rangle},[/tex]
then yes, that is a valid perspective---but not one shared by all instructors, so be careful in examinations. But in any case, note that the wave function property of being normalizable (not normalized) can have important consequences.
 

Related to Normalisation and normalising wavefunctions

What is normalisation?

Normalisation is a mathematical process used in quantum mechanics to ensure that the total probability of a particle being found in all possible states is equal to 1. In other words, it ensures that the wavefunction is properly scaled and represents a physically meaningful probability.

Why is normalisation important in quantum mechanics?

Normalisation is important because it allows us to calculate the probability of finding a particle in a particular state. Without normalisation, the wavefunction would not accurately represent the probability of finding a particle in different states, making it difficult to make predictions and draw conclusions about quantum systems.

How do you normalise a wavefunction?

To normalise a wavefunction, you need to integrate the square of the wavefunction over all possible positions or states. The result of this integration is then used to determine a normalisation constant, which is multiplied by the original wavefunction to scale it to a total probability of 1.

What is the role of normalisation in the Schrödinger equation?

The Schrödinger equation is a fundamental equation in quantum mechanics that describes the time evolution of a quantum system. Normalisation is required for the Schrödinger equation to be a valid description of a quantum system, as it ensures that the total probability of finding a particle is always equal to 1 at any point in time.

Can a wavefunction be normalised to a value other than 1?

No, the total probability of a particle being found in all possible states must always equal 1, so the wavefunction must be normalised to a value of 1. Any other value would not accurately represent the probability of finding a particle in different states and would violate the fundamental principles of quantum mechanics.

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