Calculate ΔHo for the chemical reaction:

In summary, the conversation revolves around calculating the heat of reaction using bond enthalpies. The correct formula for this calculation is ΔH° = ∑ΔHBroken - ∑ΔHFormed. The answer to the given problem is -108 kJ, not +108 kJ. This is because positive bond enthalpies result in negative values for ΔH°.
  • #1
AMan24
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Homework Statement


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Homework Equations


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The Attempt at a Solution


2(255) - [(1)(159) + (1)(243)]
= +108KJ

The answer key says its b) -108KJ. Am i doing something wrong or is the book wrong?
 
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  • #2
When using bond enthalpies, the way you calculate the heat of reaction is
[tex]\Delta H° = \sum \Delta H_{\textrm{Broken}} - \sum \Delta H_{\textrm{Formed}}[/tex]
As in, "the sum of enthalpy changes by broken bonds minus the sum of enthalpy changes by formed bonds." So, the correct answer is -108 kJ.
 
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  • #3
ΔH° is not the same thing as a bond enthalpy. Quite the opposite - positive bond enthalpy means negative ΔH° (think why).
 
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Related to Calculate ΔHo for the chemical reaction:

What is ΔHo?

ΔHo, or standard enthalpy of formation, is the change in enthalpy that occurs in a chemical reaction when one mole of a substance is formed from its constituent elements in their standard states.

How do you calculate ΔHo?

ΔHo can be calculated using the following equation: ΔHo = ΣnΔHof(products) - ΣnΔHof(reactants), where n is the number of moles of each substance and ΔHof is the standard enthalpy of formation for that substance.

What is the significance of ΔHo?

ΔHo provides information about the energy changes that occur during a chemical reaction and can be used to determine the feasibility of a reaction. A negative ΔHo indicates that the reaction is exothermic, while a positive ΔHo indicates that the reaction is endothermic.

How does temperature affect ΔHo?

ΔHo is typically measured at a standard temperature of 25°C. However, as temperature increases, the value of ΔHo may also change due to changes in the energy levels of the reactants and products. Therefore, it is important to specify the temperature at which ΔHo is measured.

Can ΔHo be negative?

Yes, ΔHo can be negative, indicating that the reaction is exothermic and releases energy. This means that the products have a lower enthalpy than the reactants, resulting in a negative change in enthalpy.

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