C-G coefficients and Angular momentum

In summary: So we can now writeIn summary, when adding angular momenta, the terms in the linear combination may have all the values of ##j## that satisfy the triangle inequality, not just the two extremal values. The component of the total angular momentum along the quantization axis must be conserved. The unknown factor in the linear combination is determined by orthogonality and normalization constraints.
  • #1
QuarkDecay
47
2
Can someone explain to me how we find it?
Examples

Y10X-=
= |1,0>|1/2,-1/2> = √2/3 |3/2,-1/2> + √1/3|1/2,-1/2>

Y11X-=
= |1,1>|1/2,-1/2> = √1/3|3/2,1/2> + √2/3|1/2,1/2>

Y2-1X- =
= √4/5 | 5/2, -3/2> + √1/5 | 3/2, -3/2>

I understand it goes like YlmX± = |l,m>|s,ms> = a |jmax, ?> + b |jmin, ?> and a,b is from the (C-G) coefficients, but I can't find how the ? comes up. I thought it was m-ms or ms-m but it doesn't match all of the examples.
 
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  • #2
When you add angular momenta, say ##l## and ##s## so that ##\vec l+\vec s = \vec j##, you have terms like ##| l, m_l\rangle |s, m_s\rangle## that you want to write as a linear combination of the ## |j, m_j\rangle## states. First note that the terms that appear in the linear combination may have all the values of ##j## that satisfy the triangle inequality, i.e. ##j_{min} \leq j \leq j_{max}##, not just the two extremal values. Also, the component of the total angular momentum along the quantization axis must be conserved, i.e. ##m_l+m_s=m_j##. In all the examples you have posted the ? is that sum.
 
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  • #3
QuarkDecay said:
Can someone explain to me how we find it?

Let ##|j_1, m_1\rangle |j_2, m_2\rangle## be the state in which the first system has angular momentum ##j_1## and z-component ##m_1##, and the second system has angular momentum ##j_2## and z-component ##m_2##. Let ##|j, m\rangle## in which the total angular momentum is ##j## and the total z-component is ##m##.

Since the z-component of angular momentum, ##m##, is additive, we know that

##|j_1, m_1\rangle |j_2, m_2\rangle = ## some combination of terms of the form ##|j, m\rangle## where
##|j_1 - j_2| \leq j \leq j_1 + j_2## and
##-j \leq m \leq +j##

To start with, it's clear that if ##m_1 = j_1## and ##m_2 = j_2##, then there is only one possibility:

1. ##|j_1, j_1\rangle |j_2, j_2\rangle = |(j_1 + j_2), (j_1 + j_2)\rangle## (The case with ##j = j_1 + j_2## and ##m = m_1 + m_2##)

Now, we use the lowering operators:

2. ##J^- = J_1^{-} + J_2^{-}##

You use the fact that
3. ##J^{-} |j, m\rangle = \sqrt{j (j+1) - m (m-1)}|j, m-1\rangle##
4. ##J_1^{-} |j_1, m_1\rangle |j_2, m_2\rangle = \sqrt{j_1 (j_1+1) - m_1 (m_1-1)}|j_1, m_1 - 1\rangle |j_2, m_2\rangle##
5. ##J_2^{-} |j_1, m_1\rangle |j_2, m_2\rangle = \sqrt{j_2 (j_2+1) - m_2 (m_2-1)}|j_1, m_1\rangle |j_2, m_2 - 1\rangle##

(##J_1^{-}## doesn't affect ##|j_2, m_2\rangle## and ##J_2^{-}## doesn't affect ##|j_1, m_1\rangle##)

So applying ##J_1^{-} + J_2^{-}## to the left side of equation 1, and applying ##J^{-}## to the right side gives us:

6. ##\sqrt{j_1 (j_1+1) - m_1 (m_1-1)} |j_1, j_1 - 1\rangle |j_2, j_2\rangle ##
##+ \sqrt{j_2 (j_2+1) - m_2 (m_2-1)} |j_1, j_1\rangle |j_2, j_2 - 1\rangle##
##= \sqrt{(j_1 + j _1)(j_1+j_2 +1) - (j_1 + j_2) (j_1 + j_2 -1)} |(j_1 + j_2), (j_1 + j_2 - 1)\rangle##

You can continue using ##J^{-}## to get all the coefficients for ##|j, m\rangle## with ##j = j_1 + j_2##.

Now, let's look at the case where ##j = j_1 + j_2 - 1##. How do you figure out that case? Well, let's look at the case ##j = j_1 + j_2 - 1## and ##m = j_1 + j_2 - 1##. We know that that has to be some combination of ##m_1 = j_1, m_2 = j_2 -1## and ##m_1 = j_1, m_2 = j_2##. Those are the only two ways to get ##m = m_1 + m_2##. So we know that there must be coefficients ##\alpha## and ##\beta## such that:

##\alpha |j_1, j_1 - 1\rangle |j_2, j_1\rangle + \beta |j_1, j_1\rangle |j_2, m_2 - 1\rangle = |(j_1 + j_2 - 1), (j_1 + j_2 - 1)\rangle##

So we have to figure out what ##\alpha## and ##\beta## must be. That's two unknowns. But we also have two constraints: (1) This state must be orthogonal to the state ##|(j_1 + j_2), (j_1 + j_2 - 1)\rangle##, and (2) ##|\alpha|^2 + |\beta|^2 = 1## (it has to be normalized). Those two constraints uniquely determine ##\alpha## and ##\beta## up to an unknown phase factor. (I'm not sure if there is some standard convention for picking the phase).

Once you know ##|j, m\rangle## for the case ##j = j_1 + j_2 - 1##, ##m = j_1 + j_2 - 1##, you can again use the lowering operators to find the states for all other values of ##m##.

Then you can again use orthogonality to find the state ##|j, m\rangle## with ##j = j_1 + j_2 - 2## and ##m = j_1 + j_2 - 2##.

Continuing in this way, you can find all the possibilities for ##|j, m\rangle##.
 
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Related to C-G coefficients and Angular momentum

1. What are C-G coefficients and how are they related to angular momentum?

C-G coefficients, also known as Clebsch-Gordan coefficients, are mathematical values used to calculate the coupling between two angular momenta in quantum mechanics. They are used to determine the probability of a particular state of angular momentum for a system of particles.

2. How are C-G coefficients calculated?

C-G coefficients are calculated using the Wigner-Eckart theorem, which uses group theory to relate the coupling between two angular momenta to the coupling between the individual angular momenta and the total angular momentum of the system.

3. What is the significance of C-G coefficients in quantum mechanics?

C-G coefficients play a crucial role in understanding the behavior of particles at the quantum level. They are used in calculations involving the angular momentum of particles and are essential for understanding phenomena such as atomic and molecular spectra.

4. Can C-G coefficients be negative?

Yes, C-G coefficients can be negative. The sign of the coefficient depends on the relative orientation of the two angular momenta being coupled. A positive coefficient indicates a constructive interference, while a negative coefficient indicates a destructive interference.

5. How do C-G coefficients affect the selection rules in atomic and molecular spectroscopy?

C-G coefficients play a crucial role in determining the allowed transitions between energy levels in atomic and molecular systems. The selection rules for these transitions depend on the values of the C-G coefficients, which dictate the probability of a particular transition occurring.

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