Recent content by ky92

  1. K

    Problem on thermodynamics first law again

    thank you! let me think about it...
  2. K

    Problem on thermodynamics first law again

    for an adiabatic process, Q=0, ΔU=w+0=w w=ΔU=CvΔT... that's all i can think of i have no idea lol
  3. K

    Problem on thermodynamics first law again

    Homework Statement Consider a system consisting of 2.0 mol CO2 (assumed to be a perfect gas) at 298K confined to a cylinder of cross-section 10cm^2 at 10 atm. The gas is allowed to expand adiabatically and reversibly against a constant pressure of 1 atm. Calculate W, Q, ΔU, ΔH, and ΔT when the...
  4. K

    How Do You Calculate Thermodynamic Quantities for a Compressed Diatomic Gas?

    thx! do u mean that ΔH=CpΔT even in an isochoric process?? so, for an isothermal process, ΔH=CpΔT = 0 for an isochoric process, ΔH=CpΔT for an isobaric process, ΔH = Q= ΔU+Δ(PV)=CpΔT in reversible isobaric process am i correct? oh my god so confusing
  5. K

    How Do You Calculate Thermodynamic Quantities for a Compressed Diatomic Gas?

    why would the model use ΔH = CpΔT if it is not an isobaric process? i thought q=CvΔT and ΔH=q=CpΔT in isobaric process!
  6. K

    How Do You Calculate Thermodynamic Quantities for a Compressed Diatomic Gas?

    i see! thanks a lot and could anyone answer my first question posted above...thanks
  7. K

    How Do You Calculate Thermodynamic Quantities for a Compressed Diatomic Gas?

    why Q=ΔU+W i know ΔU=q+w and it should be q=ΔU-w
  8. K

    How Do You Calculate Thermodynamic Quantities for a Compressed Diatomic Gas?

    thank you karkas. actually you remind me of another question, for isothermal process, ΔT=ΔU=0 ΔH = ΔU + Δ(PV) = ΔU + Δ(nRT) = 0+0 = 0 so for isothermal process, heat is not necessarily be zero but ΔH is always zero, while an adiabatic process, heat must be zero while ΔH can be nonzero, am i...
  9. K

    How Do You Calculate Thermodynamic Quantities for a Compressed Diatomic Gas?

    Homework Statement A sample of 3 mol of a diatomic perfect gas at 200K is compressed reversibly and adiabatically until its temperature reaches 250K. Given that Cv,m=27.5 JK-1mol-1, calculate q, w, ΔU, ΔH and ΔS. Homework Equations dS = dq/T ΔU = n(Cv,m)ΔT ΔH = n(Cp,m)ΔT The...
  10. K

    A question on second law of thermodynamics

    oh i get it now it's just because we assume the reaction is an isobaric, then isothermal process so T is constant for the second part i.e. in nR ln(V2/V1) thanks! you help me a lot i am bad in physics :P
  11. K

    A question on second law of thermodynamics

    thank you! by the way why couldn't i replace (V2/V1) by (T2/T1) in this case? (but we can replace V2/V1 by P1/P2) i don't really get it! how to decide whether we should substitute between P-V or P-T/V-T?
  12. K

    A question on second law of thermodynamics

    Homework Statement calculate the change of entropy (for the system) when 3 moles of a monatomic perfect gas, for which Cp,m = (5/2) R, is heated and compressed from 298K and 1atm to 398K and 5atm. ans: -22.1 JK-1 Homework Equations for an ideal gas, Pv=nRT for iso-choric condition...
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