Homework Statement
Consider a system consisting of 2.0 mol CO2 (assumed to be a perfect gas) at 298K confined to a cylinder of cross-section 10cm^2 at 10 atm. The gas is allowed to expand adiabatically and reversibly against a constant pressure of 1 atm. Calculate W, Q, ΔU, ΔH, and ΔT when the...
thx!
do u mean that ΔH=CpΔT even in an isochoric process??
so,
for an isothermal process, ΔH=CpΔT = 0
for an isochoric process, ΔH=CpΔT
for an isobaric process, ΔH = Q= ΔU+Δ(PV)=CpΔT in reversible isobaric process
am i correct?
oh my god
so confusing
thank you karkas.
actually you remind me of another question,
for isothermal process,
ΔT=ΔU=0
ΔH = ΔU + Δ(PV)
= ΔU + Δ(nRT)
= 0+0 = 0
so for isothermal process, heat is not necessarily be zero but ΔH is always zero,
while an adiabatic process, heat must be zero while ΔH can be nonzero,
am i...
Homework Statement
A sample of 3 mol of a diatomic perfect gas at 200K is compressed reversibly and adiabatically until its temperature reaches 250K. Given that Cv,m=27.5 JK-1mol-1, calculate q, w, ΔU, ΔH and ΔS.
Homework Equations
dS = dq/T
ΔU = n(Cv,m)ΔT
ΔH = n(Cp,m)ΔT
The...
oh i get it now
it's just because we assume the reaction is an isobaric, then isothermal process
so T is constant for the second part i.e. in nR ln(V2/V1)
thanks!
you help me a lot
i am bad in physics :P
thank you!
by the way
why couldn't i replace (V2/V1) by (T2/T1) in this case? (but we can replace V2/V1 by P1/P2)
i don't really get it!
how to decide whether we should substitute between P-V or P-T/V-T?
Homework Statement
calculate the change of entropy (for the system) when 3 moles of a monatomic perfect gas, for which Cp,m = (5/2) R, is heated and compressed from 298K and 1atm to 398K and 5atm.
ans: -22.1 JK-1
Homework Equations
for an ideal gas, Pv=nRT
for iso-choric condition...